Chemistry: Matter and Change

Chapter 17: Chemical Equilibrium

Standardized Test Practice

1
What is the equilibrium constant expression for the following reaction?

H2 + I2 <–> 2HI
A)Keq = [HI]2/[H2][I2]
B)Keq = [H2][I2]/ [HI]2
C)Keq = [HI]2/[H]2[I]2
D)Keq = [2HI]/ /[H2][I2]
2
When the system A + B ↔ C + D is at equilibrium, ___________.
A)the forward reaction has stopped
B)the reverse reaction has stopped
C)both the forward and reverse reactions have stopped
D)neither the forward nor the reverse reaction has stopped
3
What is the equilibrium constant expression for the following reaction

2NH4NO3(s) → 2NH3(g) + 2NO(g) + H2(g) + 2O2(g)
A)Keq = [NH3][NO][H2][O2]
B)Keq = [NH3]2[NO]2[H2][O2]2
C)Keq = ([NH3][NO][H2][O2])/[NH4NO3]
D)Keq = ([NH3]2[NO]2[H2][O2]2)/[NH4NO3]2
4
In the diagram, iodine is changing from a solid to a gas and back again in both flasks. Which flask is at chemical equilibrium?

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A)both
B)neither
C)left flask only
D)right flask only
5
The Keq at 298 K for the reaction shown below is 4.6 x 10-31. What does this small value of Keq mean?

N2(g) +O2(g) yields 2NO(g)
A)Almost all nitrogen and oxygen react to form NO.
B)Almost no nitrogen and oxygen react to form NO.
C)The reaction is impossible.
D)The reaction happens very quickly.
6
For the system, H2(g) + CO2(g) → H2O(g) + CO(g) at equilibrium, the addition of H2(g) would cause ____________.
A)only more H2O to form
B)only more CO to form
C)more H2O and CO to form
D)only more CO2 to form
7
For the reaction, 2SO2(g) + O2(g) → 2SO3(g) at equilibrium, what will be the effect on the net amount of SO3 present if the volume of the container is increased?
A)The concentration of SO3 will increase.
B)The concentration of SO3 will decrease.
C)The concentration of SO3 will remain the same.
D)This question cannot be answered without knowing the value of Keq.
8
For the gas phase reaction, SO2(g) + ½O2(g) → SO3(g), ΔH° = -1.6 × 102 kJ for the forward reaction. To increase the yield of SO3, the reaction should be run at ________.
A)high pressure and high temperature
B)high pressure and low temperature
C)low pressure and high temperature
D)low pressure and low temperature
9
For the reaction, 2NOCl(g) +75 kJ → 2NO(g) + Cl2(g), which of the following will shift the reaction to the left?
A)add a catalyst
B)heat the reaction vessel
C)decrease the volume of the container
D)add more NOCl
10
In the reaction CO(g) + 3H2(g) yields CH4(g) +H2O(g), why does increasing the pressure shift the reaction to the right.

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A)Increased pressure increases the temperature.
B)Increased pressure drives the molecules closer together.
C)Fewer moles on the right counteracts increased pressure.
D)Fewer moles on the right increases pressure.
11
The molar solubility for BaCO3 is 9.0 x 10-5M at 25°C. What is the solubility product constant, Ksp, for BaCO3?
A)1.2 x 10-8
B)8.1 x 10-9
C)5.3 x 10-12
D)4.0 x 10-15
12
If NaCl is added to a 0.010M solution of AgNO3 in water at 25°C, what will be [Cl-] when precipitation of AgCl begins? The Ksp for AgCl is 1.8 x 10-10.
A)1.0 x 10-10M
B)1.3 x 10-6M
C)1.8 x 10-8M
D)1.8 x 10-12M
13
How many grams of MgF2 will dissolve in 150 mL of 0.100M NaF solution? Ksp for MgF2 is 6.4 x 10-9.
A)6.4 x 10-7 g
B)4.1 x 10-6 g
C)1.0 x 10-5 g
D)6.0 x 10-6 g
14
Use the table to find Ksp at 298 K, then calculate the molar solubility of PbSO4.

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A)1.6 x 10-4 M
B)3.2 x 10-4 M
C)4.8 x 10-4 M
D)6.4 x 10-4 M
15
Find Qsp for AgI if 50.0 mL of 0.1 M NaI is added to 50 mL of 0.1M AgNO3. Will a precipitate form? Ksp for AgI is 8.5 x 10-17.

AgI(s) yields Ag+(aq) + I-(aq)
A)0.01, a precipitate will form
B)0.0025, a precipitate will form
C)0.01, a precipitate will not form
D)0.0025, a precipitate will not form.
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